Anne Hathaway enjoys rare outing with husband Adam Shulman as they arrive in complementing looks at National Board of Review Awards Gala

Anne Hathaway and her husband, Adam Shulman, appeared in good spirits during a rare outing in New York City on Thursday.

The 41-year-old actress and the film producer, 42, made a stylish duo who complemented black ensembles as they attended the National Board Of Review Awards Gala.

She threw a black blazer over her shoulders to stay warm in her plunging, sparkly dress as she walked onto 42nd Street with her longtime partner Cipriani.

For the special occasion, the Mother’s Instinct star — who was spotted with her co-star, Jessica Chastain, at the star-studded event — slipped into a figure-hugging dress with sequin embroidery.

She wore shiny black pumps as she stepped into the gala with Shulman by her side.

Anne Hathaway and her husband, Adam Shulman, appeared in good spirits during a rare outing in New York City on Thursday. The 41-year-old actress and the film producer, 42, made a stylish duo who complemented black ensembles as they attended the National Board Of Review Awards Gala.

To give her look an extra touch of glamour, she wore dangling diamond earrings and some statement gemstone rings in addition to her gold wedding band.

She left her chocolate brown locks in a voluminous, straight hairstyle and opted for a bronze makeup look paired with a mauve pink lip.

Shulman wore a classic black suit with a satin tie and shiny dress shoes to match Hathaway’s look.

The Devil Wears Prada alumna has been married to the jewelry designer since 2012 and has two children together.

The couple first met through mutual friends at the Palm Springs Film Festival in April 2008.

They started dating in November of the same year in the wake of her breakup with her ex-con ex-boyfriend Raffaello Follieri.

Hathaway and Follieri dated for four years before he was arrested and charged with 15 counts of conspiracy, wire fraud and money laundering.

She broke off their relationship ten days before he pleaded guilty and was sentenced to four and a half years in prison.

She threw a black blazer over her shoulders to stay warm in her plunging, sparkly dress as she walked onto 42nd Street with her longtime partner Cipriani.

She threw a black blazer over her shoulders to stay warm in her plunging, sparkly dress as she walked onto 42nd Street with her longtime partner Cipriani.

For the special occasion, the Mother's Instinct star donned a figure-hugging dress with embroidered sequins.  She wore shiny black pumps as she stepped into the gala with Shulman by her side

For the special occasion, the Mother’s Instinct star donned a figure-hugging dress with embroidered sequins. She wore shiny black pumps as she stepped into the gala with Shulman by her side

Shulman wore a classic black suit with a satin tie and shiny dress shoes to match Hathaway's look.  The Devil Wears Prada alumna has been married to the jewelry designer since 2012 and has two children together

Shulman wore a classic black suit with a satin tie and shiny dress shoes to match Hathaway’s look. The Devil Wears Prada alumna has been married to the jewelry designer since 2012 and has two children together

At the gala, they were spotted mingling with Bradley Cooper

At the gala, they were spotted mingling with Bradley Cooper

At the A-list event, Anne was also joined by Andrew Scott and Jessica Chastain as they all posed for the camera together

At the A-list event, Anne was also joined by Andrew Scott and Jessica Chastain as they all posed for the camera together

Andrew seemed excited to see Anne as he smiled sweetly and held her hands as they greeted each other

Andrew seemed excited to see Anne as he smiled sweetly and held her hands as they greeted each other

Andrew looked dapper in a gray studded suit as he had an animated chat with Hollywood actress Jessica

Andrew looked dapper in a gray studded suit as he had an animated chat with Hollywood actress Jessica

The pair were also joined by Laura Linney, who cut an elegant figure in a black dress with puffed sleeves

The pair were also joined by Laura Linney, who cut an elegant figure in a black dress with puffed sleeves

Mark sat on a table next to Mark Ruffalo, whose new film Poor Things recently hit screens

Mark sat on a table next to Mark Ruffalo, whose new film Poor Things recently hit screens

Five years later, in February 2013, Hathaway said it was love at first sight when she met Shulman amid the chaos.

She told Harper’s Bazaar UK that she knew “from the moment I met him that he was the love of my life,” but admitted that she “also knew that I couldn’t have met him at a worse time.”

After four years together, the two got engaged in 2011.

The following year, in September, they married in a traditional Jewish, intimate wedding ceremony in Big Sur, California.

The longtime couple welcomed sons Jonathan and Jack in 2016 and 2019, respectively.