Demi Lovato wows in black and white gown with velvet gloves as she attends UNICEF Gala in NYC

Demi Lovato beamed Tuesday night as she attended the annual UNICEF Gala in New York.

The 30-year-old pop star exuded sophistication in a black and white Hellessy off-the-shoulder dress with opera gloves.

The former Disney star was stunned by her performance at the star-filled event.

Captivating: Demi Lovato was beaming Tuesday night as she attended the annual UNICEF Gala in New York

Lovato turned heads in the eye-catching dress, which featured an ivory jacket-like bodice with bows on the sleeves.

It featured short sleeves, a center pleat detail and a floor-dusting hemline to complement the A-line silhouette.

Her look was created with the help of stylist Dianne Garcia, who added jewelry by David Yurman and footwear by Stuart Weitzman.

The artist wore her short haircut with a sultry fringe that framed the face, adding a feminine touch to the edgy look.

Stellar: The 30-year-old pop star exuded sophistication in a black and white Hellessy off-the-shoulder dress with opera gloves

Wow! The former Disney star was stunned by her performance at the star-filled event

The unforgettable look allowed Demi to show off the “love” and “fear” tattoos on either side of her shoulders, as well as her cobweb ink.

She turned heads in the bold look with makeup by famed artist Jill Powell and hair by Cesar Deleon Ramirez.

Lovato, who is dating her collaborator Jute$, looked better than ever with her full brows expertly arched.

Powell added a soft peach shadow to her eyelids and lined and blushed her cheeks.

Tattooed: The unforgettable look allowed Demi to show off the ‘love’ and ‘fear’ tattoos on either side of her shoulders

Details: Lovato turned heads in the eye-catching dress featuring an ivory jacket-like bodice with bows on the sleeves

The megastar’s brown eyes were brought out with the help of long, sleek lashes and mascara on her lower lash line.

The look was tied together with the addition of a glassy gloss on top of a brownish-pink lipstick.

Demi wore large diamond stud earrings in her ears and wore super-sized diamond rings over her gloves.

The gala raises funds and highlights UNICEF’s global efforts to “ensure every child is healthy, educated, respected and protected,” according to the website.

Flashy: Demi wore big diamond stud earrings in her ears and wore super-sized diamond rings over her gloves

Dazzling: The singer-songwriter’s look was a striking contrast to the blue step-and-repeat backdrop

Also appearing at the event was actress Alyssa Milano, 49, who made her presence known in a deep blue pantsuit.

The former Charmed star paired the velvet co-ord with a silky ivory top draped in horizontal pearls.

She seemed in good spirits as she happily posed for the fling before going inside.

The New York-born entertainer rocked an updo, her light brown locks in a deep side parting and side-swept bangs.

Attendee: Actress Alyssa Milano, 49, also appeared at the event, making her presence known in a deep blue pantsuit

Glamorous: The former Charmed star paired the velvet combo with a silky ivory top draped in horizontal pearls

Alyssa was accompanied by actress and disability rights activist Aria Mia Loberti, who shone in a red dress.

The star of the upcoming Netflix movie All the Light We Cannot See looked gorgeous in the short-sleeved look, which featured a tie color.

Photo op: Alyssa was joined by actress and disability rights activist Aria Mia Loberti, who sparkled in a red dress

Supporter: Also present at the meeting was 56-year-old UNICEF Ambassador Tea Leoni

Also present at the meeting were longtime UNICEF Ambassador Tea Leoni, 56, and Chief Philanthropy Officer Renée Cutting.

Leoni, whose grandmother co-founded the organization, proudly wore a blue T-shirt with the agency’s logo.

She paired it with a black blazer and a long black skirt, tucking the T-shirt into it.

For her part, Cutting looked great in a sleeveless dress with a nude base and an embossed turquoise pattern all over.

Beauty: Chief Philanthropy Officer Renée Cutting looked great in a sleeveless dress with a nude base and an embossed turquoise pattern